Cosmetic make-up composition

ABSTRACT

A cosmetic make-up composition comprises, in combination, cosmetic make-up components and, as a binding agent therefor, an intimate mixture of from 5 to 95 percent by weight of said mixture of finely divided silica and about 95 to about 5 percent by weight of said mixture of finely divided polyethylene fibers having a fibrillar structure.

This application is a continuation-in-part of application Ser. No.06/909,725, filed Sept. 22, 1986, now abandoned, which is a continuationof application Ser. No. 06/540,752, filed Oct. 11, 1983, now U.S. Pat.No. 4,659,562.

The present invention relates to a cosmetic facial make-up composition.

Cosmetic make-up compositions for the face such as eyelid shadow orliner, cheek rouge, anti-circle or cover formulations, lipsticks and thelike improve facial esthetics by imparting more relief to the face, eyesand lips and by intensifying their color.

These compositions can be provided in aqueous or anhydrous form incolors suitable to the individual user and they are applied to thesurface of the skin of the eyelids or the lips.

One disadvantage encountered most frequently during the use of cheekrouge and eyelid shadow reside in the fact that after a certain lapse oftime, the composition, due to wrinkling of the skin and the eyelids, hasa tendency to lose its uniformity and to concentrate more or lessrapidly and deeply in the folds of the skin. It results from it aneffect considered generally unaesthetic.

Despite numerous investigations in this area, it has not heretofore beenpossible to perfect make-up products capable of maintaining theiruniformity during more or less prolonged periods of time, that is tosay, having properties commonly termed "creaseproof".

The present invention provides a very satisfactory solution to thisproblem by using a novel binding agent in cosmetic make-up composition.

The studies that have been carried out have, in effect, shown that themake-up compositions containing this binding agent do not cause theformation of unaesthetic folds; they prevent the migration of themake-up, and they do not require, consequently, new or repeatedapplications as is most often the case with conventional make-upcompositions.

The present invention thus relates to a cosmetic make-up compositioncontaining as the binding agent, an intimate mixture of 5 to about 95weight percent of said mixture of finely divided silica and about 95 toabout 5 weight percent of said mixture of finely divided polyethylenefibers having a fibrillar structure.

The binding agent of the make-up compositions of the present inventionis preferably obtained by the pulverization by fluid energy of silicaand polyethylene, for example with the aid of a micronizer.

The co-pulverization of polyethylene fibers and silica reduces theparticle size of the silica, defibrillates the polyethylene fibers andproduces an intimate mixture, the polyethylene fibers and the silicaparticles being maintained together and not being able to be separatedby conventional mechanical means.

The polyethylene of this intimate mixture has a molecular weight greaterthan about 400,000, a softening point in the order of 120°-130° C. and amelting point in the order of 130 to about 135° C. The finely dividedpolyethylene contains an amount greater than about 90 weight percent offibers having an average length in the order of about 10μand a diameterlower than about 1μ. Preferably the polyolefin fibers are very fibrillarand have a very high specific area, generally between 5 and 15m² /g.

The silica is preferably a silica aerogel (synthetic amorphous silica)having an average particle diameter in the order of 2 to about 10μ, asurface area in the order of 300 to about 400m^(2/) g, a pore volume ofat least about 1.2cm³ /g and an average pore diameter in the order of150 to about 250A.

In accordance with a particular embodiment of the present invention thisintimate mixture contains between about 45 and about 75% and preferablybetween 50 to 60% by weight of silica aerogel having an average diameterin order of 2 to about 10μ, and between about 55 and 25% and preferablybetween 40 and 50% by weight of finely divided polyethylene fibershaving a specific area between 5 and 15m² /g.

The binding agent of the cosmetic make-up compositions according to thepresent invention, such as defined above, can be one of those describedin French Pat. No. 81.03535 and is principally a product sold by W. R.Grace & Co. under the tradename "SP5-1776" (60% amorphous silica--40%low density polyethylene having a specific area of 6 to 10m² /g) or"SP5-2076" (50% amorphous silica--50% low density polyethylene having aspecific area of 6 to 10m² /g).

The binding agent is generally present in an amount between 0.5 and 20percent by weight of the composition of the present invention.

The make-up composition in accordance with the present invention can beprovided in anhydrous or aqueous form. In this latter case thecomposition is generally an emulsion of the oil-in-water or water-in-oiltype or a suspension.

When the make-up composition of the present invention is provided inanhydrous form, the composition is generally a product containing afatty body and optionally one or more organic solvents.

When the make-up composition according to the invention is provided inanhydrous fatty form, it comprises, generally 0.5 to 20 weight percentbinding agent, 5 to 98 weight percent of a fatty body, 0,5 to 40 weightpercent and preferably 1 to 30 weight percent of a mineral or organiccharge, 0 to 80 weight percent of a solvent and 0 to 30 weight percentand preferably 1 to 25 weight percent of one or more colored pigments.

The mineral or organic charges of the above anhydrous compositions arepreferably talc, rice starch, wheat starch, corn starch, oat or wheatgerm powder and kaolin.

The fatty body is at least one oil or a mixture of at least one oil andat least one wax.

Representative oils usefully employed in accordance with the presentinvention include:

mineral oils such as paraffin oil, petrolatum oil and mineral oilshaving a boiling point between 310° and 410° C.,

oils of animal origin such as Purcellin oil, perhydrosqualene andcalophyllum oil,

vegetable oils such as sweet almond oil, palm oil, avocado oil, oliveoil, ricin oil, the oil of cereal germs such as the oil of wheat germ,

silicone oils such as dimethyl polysiloxane

synthetic esters such as butyl myristate, isopropyl myristate, cetylmyristate, isopropyl palmitate, butyl stearate, hexadecyl stearate,isopropyl stearate, octyl stearate, isocetyl stearate, decyl oleate,hexyl laurate, propylene glycol dicaprylate, and diisopropyl adipate,

organic alcohols such as oleyl alcohol, linoleic alcohol, linolenicalcohol, isostearyl alcohol and octyl dodecanol,

esters derived from lanolic acid such as isopropyl lanolate and isocetyllanolate, as well as

other oils, such as acetyl glycerides, the octanoates and decanoates ofalcohols and polyalcohols such as those of glycol and glycerol, thericinoleates of alcohols and polyalcohols such as that of cetyl.

Representative waxes usefully employed in accordance with the presentinvention include

mineral waxes such as microcrystalline waxes, paraffin wax andpetrolatum wax,

fossil waxes such as ozokerite and montan wax,

waxes of animal origin such as beeswax, spermaceti wax, lanolin wax,derivatives proceeding from lanolin such as lanolin alcohols,hydrogenated lanolin, hydroxylated lanolin, acetylated lanolin, lanolinfatty acids and the alcohol of acetylated lanolin,

waxes of vegetable origin such as candellila wax, Carnauba wax, Japanwax and cocoa butter,

hydrogenated oils which are solid at 25° C. such as hydrogenated ricinoil, hydrogenated palm oil, hydrogenated tallow and hydrogenated coconutoil,

synthetic waxes such as polyethylene waxes, copolymerized polyethylenewaxes,

fatty esters which are solid at 25° C. such as propylene glycolmonomyristate and myristyl myristate,

silicone waxes such as methyloctadecane-oxypolysiloxane andpoly(dimethylsiloxy)stearyl-oxysiloxane,

as well as other waxes such as cetyl alcohol, stearyl alcohol, mono-,di- and triglycerides solid at 25° C., stearyl monoethanolamide, rosinand its derivatives such as glycol and glycerol abietates, sucroglycerides and the oleates, myristates, lanolates, stearates anddihydroxy stearates of calcium, magnesium, zinc and aluminum.

Representative solvents usefully employed in the present inventioninclude isoparaffins, linear or cyclic silicones having a boiling pointlower than 200° C., chlorinated solvents and the like.

Representative colored pigments usefully employed in the presentinvention include carbon black or black iron oxide, chromium oxides,yellow, brown and red iron oxides, the ultramarines (polysulfides ofaluminosilicates) manganese pyrophosphate, ferric blue, titanium dioxideas well as certain metallic powders such as those of silver of aluminum.The pigments are most often used in admixture with nacreous agents suchas bismuth oxychloride, mica-titanium and guanine crystals, as well aswith certain organic dyes, such as carmine and organic lakes.

Moreover, the cosmetic make-up compositions of the present invention canalso contain anti-oxidant agents, such as the propyl, octyl and dodecylesters of gallic acid, butyl hydroxy anisole, butyl hydroxy toluene andnordihydroguaiaretic acid, as well as perfumes, preservatives orthickening agents, such as cellulose derivatives, xanthene gums, guargums, carob bean gums, alginates and carreghenates, silicate complexesand organically modified clays.

When the cosmetic make-up of the present invention is provided in theform of a water-in-oil emulsion, this emulsion comprises 5 to 80 weightpercent of a water phase, 1 to 40 weight percent of an oil phase, 2 to15 weight percent of an emulsifying agent 0.5 to 20 weight percent ofthe binding agent as defined above 0.5 to 40 weight percent andpreferably 1 to 30 weight percent of a mineral or organic charge, 0 to20 weight percent of a thickening agent and 0 to 30 weight percent andpreferably 1 to 25 weight percent of at least one colored pigment.

When the cosmetic make-up of the present invention is provided in theform of a water-in-oil emulsion, this emulsion comprises 1 to 96.5weight percent of a water phase, 1 to 30 weight percent of an oil phase,1 to 15 weight percent of an emulsifying agent, 0.5 to 20 weight percentof the binding agent as defined above, 0,5 to 40 weight percent andpreferably 1 to 30 weight percent of a mineral or organic charge, 0 to20 weight percent of a thickening agent and 0 to 30 weight percent andpreferably 1 to 25 weight percent of at least one colored pigment.

The oil phase of these emulsions can comprise at least one oil such asthose enumerated above, optionally in admixture with at least one wax,also as listed above.

Representative emulsifying agents usefully employed in these emulsionsinclude, particularly, anionic surfactants and more particularly soapsof amines or salts of lanolic acid, as well as anionic surfactants andthe like.

The mineral or organic charges as well as the colored pigments employedin these emulsions can be the same as those mentioned above with respectto the anhydrous compositions.

The cosmetic make-up compositions in accordance with the presentinvention can also contain various components such as sterols,lecithins, polyalcohols, anti-oxidant agents, perfumes, preservatives,as well as certain active products.

Representative active compounds or agents include, principally,keratolytic agents, anti-inflammatory agents, cicatrisive agents, benzylperoxide, salicylic acid, retinoic acid, collagen and the like.

The following non-limiting examples are given to illustrate the cosmeticmake-up compositions in accordance with the present invention.

    ______________________________________                                        Example 1 - Anhydrous eyelid make-up                                          Bees wax            15         g                                              Petrolatum          5          g                                              Hydrogenated ricin oil                                                                            5          g                                              Polyethylene wax    l0         g                                              Isoparaffin         44.8       g                                              Propyl parahydroxybenzoate                                                                        0.2        g                                              Talc                5          g                                              Binding agent - "SP5-1776"                                                                        2          g                                              Mica-titanium                                                                 Titanium dioxide    13         g                                              Iron oxide                                                                                        100        g                                              Example 2 - Anhydrous facial camouflage                                       Candellila wax      4          g                                              Microcrystalline wax                                                                              8          g                                              Cocoa butter        8          g                                              Isopropyl myristate 44.9       g                                              Talc                7          g                                              Butyl hydroxy toluene                                                                             0.1        g                                              Iron oxides         5          g                                              Titanium dioxide    20         g                                              Binding agent - "SP5-2076"                                                                        3          g                                              Example 3 - Lipstick                                                          Beeswax             8          g                                              Ethylene glycol dicaprylate                                                                       16.5       g                                              Paraffin            3          g                                              Carnauba wax        5          g                                              Trilaurin           10         g                                              Hydrogenated ricin oil                                                                            5          g                                              Butyl hydroxy toluene                                                                             0.1        g                                              Lanolin             1          g                                              Kaolin              5          g                                              Modified starch     5          g                                              Binding agent - "SP5-1776"                                                                        1          g                                              Isoparaffin         40.4       g                                                                  100.0      g                                              Example 4 - Lipstick                                                          Beeswax             15         g                                              Petrolatum          12         g                                              Polyethylene wax    10         g                                              Trilaurin           10         g                                              Hydrogenated ricin oil                                                                            3          g                                              Liquid lanolin      9          g                                              Butyl hydroxy toluene                                                                             0.1        g                                              Micronized talc     3          g                                              Modified starch     5          g                                              Binding agent - "SP5-1776"                                                                        0.5        g                                              Volatile silicone   32.4       g                                              ______________________________________                                    

The lipsticks of the Examples 3 and 4, applied prior to the applicationof a lip rouge, prevent the migration of the rouge on the edges of thelips and thus assure a long lasting sharp outline of the lips.

    ______________________________________                                        Example 5 - Anhydrous eyelid make-up                                          Beeswax                12        g                                            Petrolatum             5         g                                            Carnauba wax           3         g                                            Hydrogenated ricin oil 5         g                                            Polyethylene wax       10        g                                            Isoparaffin            44.8      g                                            Propyl parahydroxybenzoate                                                                           0.2       g                                            Talc                   5         g                                            Binding agent "SP5-1776"                                                                             2         g                                            Mica-titanium          6         g                                            Titanium dioxide       2         g                                            Iron oxide             5         g                                            Example 6 - Mascara in the form of an oil-in-water emulsion                   Stearic acid           2.5       g                                            Polyethoxylated sorbitan monostearate                                                                0.5       g                                            Petrolatum oil         3         g                                            Petrolatum             5         g                                            Triethanolamine        1         g                                            Carnauba wax           2         g                                            Bees wax               7         g                                            Talc                   3         g                                            Black iron oxide       5         g                                            Imidazolidinyl urea    0.3       g                                            Binding agent "SP5-1776"                                                                             1         g                                            Sterile, permutted water, amount                                                                     100       g                                            sufficient for                                                                Example 7 - Cheek make-up in the form of a                                    water-in-oil emulsion                                                         Magnesium lanolate     4         g                                            Hydrogenated lanolin   13        g                                            Paraffin oil           8         g                                            Microcrystalline wax   4.5       g                                            Ozokerite              3         g                                            Carnauba wax           5         g                                            Glycerides of saturated fatty acids                                                                  4.5       g                                            Methyl parahydroxybenzoate                                                                           0.3       g                                            Iron oxides            3.5       g                                            Corn starch            5         g                                            Mica-titanium          3         g                                            Binding agent "SP5-1776"                                                                             0.5       g                                            Sterile permutted water, amount                                                                      100       g                                            sufficient for                                                                Example 8 - Eyelid make-up in the form of an oil-in-water                     Petrolatum oil         12        g                                            Bees wax               10        g                                            Carnauba wax           7         g                                            Sodium borate          1         g                                            Propyl parahydroxybenzoate                                                                           0.15      g                                            Imidazolidinyl urea    0.30      g                                            Iron oxides            5         g                                            Corn starch            7         g                                            Mica-titanium          3         g                                            Binding agent "SP5-1776"                                                                             2.5       g                                            Sterile permutted water, amount                                                                      100       g                                            sufficient for                                                                Example 9 - Anhydrous cheek make-up                                           Paraffin oil           45        g                                            Petrolatum             12        g                                            Carnauba wax           20        g                                            Ozokerite              3         g                                            Propyl parahydroxybenzoate                                                                           0.1       g                                            Butyl hydroxy toluene  0.05      g                                            DC red 7               0.2       g                                            Iron oxides            2         g                                            Talc                   3         g                                            Corn starch            0.5       g                                            Binding agent "SP5-1776"                                                                             2         g                                            Mica-titanium          12.15     g                                            Example 10 - Anti-circle formulation in the form of a                         water-in-oil emulsion                                                         Ester of sorbitan and fatty acid                                                                     7         g                                            Isopropyl myristate    12        g                                            Bees wax               4         g                                            Carnauba wax           3         g                                            Imidazolidinyl urea    0.3       g                                            Methyl parahydroxybenzoate                                                                           0.1       g                                            Iron oxides            6.9       g                                            Talc                   5         g                                            Titanium dioxide       2         g                                            Binding agent "SP5-1776"                                                                             1         g                                            Sterile, permutted water,                                                                            100       g                                            amount sufficient for                                                         Example 11 - Cheek make-up in the form of a                                   water-in-oil emulsion                                                         Magnesium lanolate     4         g                                            Paraffin oil           8         g                                            Microcrystalline wax   4.5       g                                            Carnauba wax           5         g                                            Glycerides of saturated fatty acids                                                                  4.5       g                                            Methyl parahydroxybenzoate                                                                           0.3       g                                            Talc                   30        g                                            Binding agent "SP5-1776"                                                                             0.5       g                                            Seerile permutted water, amount                                                                      100       g                                            sufficient for                                                                Example 12 - Mascara in the form of an oil-in-water emulsion                  Stearic acid           3         g                                            Carnauba wax           2         g                                            Paraffin wax           1         g                                            Petrolatum oil         3         g                                            Ozokerite              8         g                                            Corn starch            1         g                                            Imidazolidinyl urea    0.3       g                                            Binding agent "SP5-1776"                                                                             1         g                                            Triethanolamine        2         g                                            Sterile permutted water, amount                                                                      100       g                                            sufficient for                                                                Example 13 - Anhydrous anti-circle                                            Bees wax               5         g                                            Paraffin wax           4,75      g                                            Paraffin oil           41        g                                            Microcrystalline wax   4         g                                            Propyl parahydroxybenzoate                                                                           0.2       g                                            Butyl hydroxy toluene  0.05      g                                            Iron oxides            5         g                                            Talc                   30        g                                            Binding agent "SP5-1776"                                                                             2         g                                            Mica-titanium          3         g                                            Corn starch            5         g                                            Example 14 - Anhydrous eyelid make-up                                         Microcrystalline wax   6         g                                            Petrolatum             3         g                                            Japan wax              2         g                                            Bees wax               5         g                                            Propyl parahydroxybenzoate                                                                           0.3       g                                            Wheat starch           0.5       g                                            Binding agent "SP5-1776"                                                                             2.5       g                                            Iron oxides            5         g                                            Titanium dioxide       1         g                                            Mica-titanium          6         g                                            Isoparaffin, amount sufficient for                                                                   100       g                                            ______________________________________                                    

What is claimed is:
 1. An anhydrous cosmetic make-up composition forapplication to the face, eyes or lips comprising(a) from 5 to 98 weightpercent of a fatty body selected from the group consisting of an oil anda mixture of an oil and a wax, said oil comprising a member selectedfrom the group consisting of paraffin oil, petrolatum oil, mineral oilhaving a boiling point between 310° and 410° C., Purcellin oil,perhydrosqualene, calophyllum oil, sweet almond oil, palm oil, avocadooil, olive oil, ricin oil, wheat germ oil, dimethylpolysiloxane, butylmyristate, isopropyl myristate, cetyl myristate, isopropyl palmitate,butyl stearate, hexadecyl stearate, isopropyl stearate, octyl stearate,isocetyl stearate, decyl oleate, hexyl laurate, propylene glycoldicaprylate, diisopropyl adipate, oleyl alcohol, linoleic alcohol,linolenic alcohol, isostearyl alcohol, octyl dodecanol, isopropyllanolate, isocetyl lanolate, glycol octanoate, glycerol octanoate,glycol decanoate, glycerol decanoate and cetyl ricinoleate, said waxcomprising a member selected from the group consisting of amicrocrystalline wax, paraffin wax, petrolatum wax, ozokerite, montanwax, beeswax, spermaceti wax, lanolin wax, lanolin alcohols,hydrogenated lanolin, hydroxylated lanolin, acetylated lanolin, lanolinfatty acids, alcohol of acetylated lanolin, candellila wax, Carnaubawax, Japan wax cocoa butter, hydrogenated ricin oil, hydrogenated palmoil, hydrogenated tallow, hydrogenated coconut oil, polyethylene wax,propylene glycol monomyristate, myristyl myristate, silicone wax, cetylalcohol, stearyl alcohol, mono-, di- and triglycerides solid at 25° C.,stearyl monoethanolamide, rosin, glycol abietate, glycerol abietate,sucroglyceride, and the oleates, myristates, lanolates, stearates anddihydroxy stearates of calcium, magnesium, zinc and aluminum; (b) from0.5 to 40 weight percent of a mineral or organic charge selected fromthe group consisting of talc, rice starch, wheat starch, corn starch,oat or wheat germ powder and kaolin; (c) from 0 to 80 weight percent ofa solvent comprising a member selected from the group consisting ofisoparaffins, linear or cyclic silicones having a boiling point lowerthan 200° C. and chlorinated solvents; (d) from 0 to 30 weight percentof at least one colored pigment selected from the group consisting ofblack iron oxide, carbon black, chromium oxide, yellow iron oxide, browniron oxide, red iron oxide, ultramarine, titanium dioxide, silvermetallic powder, aluminum metallic powder, manganese pyrophosphate,ferric blue, carmine and organic lakes; and (e) from 0.5 to 20 weightpercent, as a binding agent for components (a)-(d), above, a mixture offrom 5 to 95 percent by weight of said mixture of finely divided silicahaving an average particle diameter of from 2 to about 10μ and about 95to about 5 percent by weight of said mixture of finely dividedpolyethylene fibers having a fibrillar structure and having a specificarea of 5 to 15m² /g.
 2. The cosmetic make-up composition of claim 1wherein said colored pigment is present in an amount from 1 to 25 weightpercent.
 3. The cosmetic make-up composition of claim 1 wherein saidmineral or organic charge is present in an amount from 1 to 30 weightpercent.
 4. The cosmetic make-up composition of claim 1 wherein saidbinding agent comprises a mixture of 50 to 60 percent by weight of saidmixture of amorphous silica and from 40 to 50 percent by weight of saidmixture of low density polyethylene having a specific area of 6 to 10m²/g.
 5. A cosmetic make-up composition in the form of a water-in-oilemulsion comprising:(a) from 5 to 80 weight percent of a water phase;(b) from 1 to 40 weight percent of an oil phase; (c) from 0.5 to 40weight percent of a mineral or organic charge selected from the groupconsisting of talc, rice starch, wheat starch, corn starch, oat or wheatgerm powder and and kaolin. (d) from 0 to 30 weight percent of at leastone colored pigment selected from the group consisting of black ironoxide, carbon black, chromium oxide, yellow iron oxide, brown ironoxide, red iron oxide, ultramarine, titanium dioxide, silver metallicpowder, aluminum metallic powder, manganese pyrophosphate, ferric blue,carmine and organic lakes; and (e) from 0.5 to 20 weight percent, as abinding agent for components (a)-(d), above, a mixture of from 5 to 95percent by weight of said mixture of finely divided silica having anaverage particle diameter of from 2 to about 10μ and about 95 to about 5percent by weight of said mixture of finely divided polyethylene fibershaving a fibrillar structure and having a specific area of 5 to 15m² /g.6. The cosmetic make-up composition of claim 5 wherein said coloredpigment is present in an amount from 1 to 25 weight percent.
 7. Thecosmetic make-up composition of claim 5 which also contains anemulsifying agent in an amount from 2 to 15 weight percent.
 8. Thecosmetic make-up composition of claim 5 wherein said binding agentcomprises a mixture of 50 to 60 percent by weight of said mixture ofamorphous silica and from 40 to 50 percent by weight of said mixture oflow density polyethylene having a specific area of 6 to 10m² /g.
 9. Acosmetic make-up composition in the form of an oil-in-water emulsioncomprising:(a) from 1 to 30 weight percent of an oil phase; (b) from 1to 96.5 weight percent of a water phase; (c) from 0.5 to 40 weightpercent of a mineral or organic charge selected from the groupconsisting of talc, rice starch, wheat starch, corn starch, oat andwheat germ powder and kaolin; (d) from 0 to 30 weight percent of atleast one colored pigment selected from the group consisting of blackiron oxide, carbon black, chromium oxide, yellow iron oxide, brown ironoxide, red iron oxide, ultramarine, titanium dioxide, silver metallicpowder, aluminum metallic powder, manganese pyrophosphate, ferric blue,carmine and organic lakes; and (e) from 0.5 to 20 weight percent, as abinding agent for components (a)-(d), above, a mixture of from 5 to 95percent by weight of said mixture of finely divided silica having anaverage particle diameter of from 2 to about 10μ and about 95 to 5percent by weight of said mixture of finely divided polyethylene fibershaving a fibrillar structure and having a specific area of 5 to 15m² /g.10. The cosmetic make-up composition of claim 9 wherein said coloredpigement is present in an amount from 1 to 25 weight percent.
 11. Thecosmetic make-up composition of claim 9 which also contains anemulsifying agent in an amount from 1 to 15 weight percent.
 12. Thecosmetic make-up composition of claim 9 wherein said binding agentcomprises a mixture of 50 to 60 percent by weight of said mixture ofamorphous silica and from 40 to 50 percent by weight of said mixture oflow density polyethylene having a specific area of 6 to 10m² /g.
 13. Thecosmetic make-up composition of claim 9 wherein said colored pigment isadmixed with a nacreous agent selected from the group consisting ofbismuth oxychloride, mica-titanium and guanine crystals.